It's amazing that this Private Practice looker wasn't scooped up sooner, but Kate Walsh didn't meet her Dr. Love, Alex Young, until she was just shy of her 40th birthday in February 2007. It was love at first sight for Kate and the movie executive, who were engaged just three months later. "I know—I'm literally living the dream," the actress told People.com at the time. "But you know when you know. I was not expecting it, so it's kind of amazing." The couple were married the following September and are currently living in bliss.

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