2005 proved to be a milestone year for Angelina. Not only did her scandalous affair with Brad Pitt become public, but she also became pregnant with his child. Here, at the screening of Mr. and Mrs. Smith, Angelina looks every bit the mega star that she is, in a daring Versace leather dress, smoldering eye makeup and blown-back hairstyle. Don't count on this new mother of three turning in her halters for housecoats any time soon.